Adjust an oven rack to the middle position and heat the oven to 375 degrees. Line a muffin tin with liners.
Whish the flour, sugar, baking powder,baking soda and salt together in a large bowl.
In a medium bowl, whisk the milk and eggs together until smooth.
Add the espresso powder and whisk until combined.
Gently fold the buttermilk mixture into the flour mixture with a spatula until combined.
Fold in the melted butter.
Fold in the chocolate chips
Divide the batter evenly among the muffin cups.
Bake until golden brown, 25-30 minutes, and a toothpick inserted in the center comes out with only crumbs.
Let cool in pan for 5 minutes before removing and placing on a wire rack to cool completely.